Search result: Catalogue data in Spring Semester 2018
Interdisciplinary Sciences Bachelor | ||||||
Physical-Chemical Direction | ||||||
2. Semester (Physical-Chemical Direction) | ||||||
Additional First Year Subjects | ||||||
Number | Title | Type | ECTS | Hours | Lecturers | |
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529-0012-03L | General Chemistry (Organic Chemistry) II | Z | 4 credits | 3V + 1U | P. Chen | |
Abstract | Classification of organic reactions, reactive intermediates: radicals, carbocations, carbanions, organic acids / bases, electronic substituent effects, electrophilic aromatic substitution, electrophilic addition to double bonds, HSAB concept, nucleophilic substitution at sp3 hybridized carbon centres (SN1/SN2 reactions), nucleophilic aromatic substitutions, eliminations. | |||||
Objective | Understanding of fundamental reactivity principles and the relationship between structure and reactivity. Knowledge of the most important raection types and of selected classes of compounds. | |||||
Content | Classification of organic reactions, reactive intermediates: radicals, carbocations, carbanions, organic acids / bases, electronic substituent effects, electrophilic aromatic substitution, electrophilic addition to double bonds, HSAB concept, nucleophilic substitution at sp3 hybridized carbon centres (SN1/SN2 reactions), nucleophilic aromatic substitutions, eliminations. | |||||
Lecture notes | pdf file available at the beginning of the course | |||||
Literature | [1] P. Sykes, "Reaktionsmechanismen der Organischen Chemie", VCH Verlagsgesellschaft, Weinheim 1988. [2] Carey/Sundberg, Advanced Organic Chemistry, Part A and B, 3rd ed., Plenum Press, New York, 1990/1991. Deutsch: Organische Chemie. [3] Vollhardt/Schore, Organic Chemistry, 2th ed., Freeman, New York, 1994 Deutsche Fassung: Organische Chemie 1995, Verlag Chemie, Wein¬heim, 1324 S. Dazu: N. Schore, Arbeitsbuch zu Vollhardt, Organische Chemie, 2. Aufl. Verlag Chemie, Weinheim, 1995, ca 400 S. [4] J. March, Advanced Organic Chemistry; Reactions, Mechanisms, and Structure, 5th ed., Wiley, New York, 1992. [5] Streitwieser/Heathcock, Organische Chemie, 2. Auflage, Verlag Chemie, Weinheim, 1994. [6] Streitwieser/Heathcock/Kosower, Introduction to Organic Chemistry, 4th ed., MacMillan Publishing Company, New York, 1992. [7] P. Y. Bruice, Organische Chemie, 5. Auflage, Pearson Verlag, 2007. | |||||
529-0012-02L | General Chemistry (Inorganic Chemistry) II | Z | 4 credits | 3V + 1U | H. Grützmacher, W. Uhlig | |
Abstract | 1) General definitions 2) The VSEPR model 3) Qualitative molecular orbital diagrams 4) Closest packing, metal structures 5) The Structures of metalloids 6) Structures of the non-metals 7) Synthesis of the elements 8) Reactivity of the elements 9) Ionic Compounds 10) Ions in Solution 11) Element hydrogen compounds 12) Element halogen compounds 13) Element oxygen compounds 14) Redox chemistry | |||||
Objective | Understanding of the fundamental principles of the structures, properties, and reactivities of the main group elements (groups 1,2 and 13 to 18). | |||||
Content | The course is divided in 14 sections in which the fundamental phenomena of the chemistry of the main group elements are discussed: Part 1: Introduction in the periodical properties of the elements and general definitions –Part 2: The VSEPR model –Part 3: Qualitative molecular orbital diagrams for simple inorganic molecules – Part 4: Closest packing and structures of metals Part 5: The Structures of semimetals (metalloids) of the main group elements –Part 6: Structures of the non-metals– Part 7: Synthesis of the elements. –Part 8: Reactivity of the elements Part 9: Ionic Compounds Part 10: Ions in Solution Part 11: Element hydrogen compounds Part 12: Element halogen compounds Part 13: Element oxygen compounds Part 14: Redox chemistry. | |||||
Lecture notes | The transparencies used in the course are accessible via the internet on Link | |||||
Literature | J. Huheey, E. Keiter, R. Keiter, Inorganic Chemistry, Principles and Reactivity, 4th edition, deGruyter, 2003. C.E.Housecroft, E.C.Constable, Chemistry, 4th edition, Pearson Prentice Hall, 2010. | |||||
Prerequisites / Notice | Basis for the understanding of this lecture is the course Allgemeine Chemie 1. |
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