529-0132-AAL Inorganic Chemistry III: Organometallic Chemistry and Homogeneous Catalysis
Semester | Frühjahrssemester 2023 |
Dozierende | C. Copéret |
Periodizität | jedes Semester wiederkehrende Veranstaltung |
Lehrsprache | Englisch |
Kommentar | Belegung ist NUR erlaubt für MSc Studierende, die diese Lerneinheit als Auflagenfach verfügt haben. Alle anderen Studierenden (u.a. auch Mobilitätsstudierende, Doktorierende) können diese Lerneinheit NICHT belegen. Dieser Kurs beinhaltet keine eigene Vorlesung, sondern bezieht sich auf die Vorlesung 529-0132-00L. |
Kurzbeschreibung | Fundamental aspects of the organometallic chemistry ot the transition elements. Mechanistic homogeneous catalysis including oxidative additions, reductive eliminations and insertion reactions. Catalytic hydrogenation, carbonylation, C-C bond-forming and related reactions. |
Lernziel | Towards an understanding of the fundamental coordination-chemical and mechanistic aspects of transition-metal chemistry relevant to homogeneous catalysis. |
Inhalt | Fundamental aspects of the organometallic chemistry ot the transition elements. Mechanistic homogeneous catalysis including oxidative additions, reductive eliminations and insertion reactions. Catalytic hydrogenation, carbonylation, C-C bond-forming and related reactions. |
Literatur | 1) Robert H. Crabtree, The Organometallic Chemistry of the Transition Metals, 6th Edition, Wiley, 2014, ISBN: 978-1-118-13807-6. A relatively concise but excellent introduction to organometallic chemistry. Strong textbook character, available as E-book 2) John F. Hartwig, Organotransition Metal Chemistry. From Bonding to Catalysis, University Science Books, 2010, ISBN: 978-1-891389-53-5. A more comprehensive standard work on organometallic chemistry. Several chapters written by various authors, partly specialized review-article style. |