René Verel: Catalogue data in Spring Semester 2018
|Name||Dr. René Verel|
Lab. für Anorganische Chemie
ETH Zürich, HCI D 117
|Telephone||+41 44 632 67 93|
|Department||Chemistry and Applied Biosciences|
|529-0144-00L||NMR Spectroscopy in Inorganic Chemistry||7 credits||3G||R. Verel|
|Abstract||Theory and applications of NMR spectroscopy with a focus of its use to problems in Inorganic Chemistry.|
The use of the Bloch Equations to describe broadband and selective excitation, measurement techniques and processing strategies of NMR data, applications of NMR to the study of molecular structure, chemical exchange processes, diffusion spectroscopy, and solid-state NMR techniques.
|Objective||In depth understanding of both practical and theoretical aspects of solution and solid-state NMR and its application to problems in Inorganic Chemistry|
|Content||Selection of the following themes:|
1. Bloch Equations and its use to understand broadband and selective pulses.
2. Measurement techniques and processing strategies of NMR data.
3. Applications of NMR to the study of molecular structure: Experiments and strategies to solve problems in Inorganic Chemistry.
4. Application of NMR to the study of chemical exchange processes.
5. Application of NMR to the study of self-diffusion and the determination of diffusion coefficients.
6. Differences and similarities between fundamental interactions in solution and solid-state NMR
7. Experimental techniques in solid-state NMR (Magic Angle Spinning, Cross Polarization, Decoupling and Recoupling Techniques, MQMAS)
8. The use of Dynamic Nuclear Polarization for the study of surfaces.
|Lecture notes||A handout is provided during the lectures. It is expected that the students will consult the accompanying literature as specified during the lecture.|
|Literature||Specified during the lecture|
|Prerequisites / Notice||529-0432-00 Physikalische Chemie IV: Magnetische Resonanz 529-0058-00 Analytische Chemie II|
|529-2002-02L||Chemistry II||5 credits||2V + 2U||W. Uhlig, J. E. E. Buschmann, S. Canonica, P. Funck, H. Grützmacher, E. C. Meister, R. Verel|
|Abstract||Chemistry II: Electrochemistry and redox reactions, chemistry of the elements, introduction to organic chemistry|
|Objective||General base for understanding problems of inorganic and organic chemistry.|
|Content||1. Redox reactions and electrochemistry|
2. Inorganic Chemistry
Rules for nomenclature of inorganic compounds. Systematic description of the groups of elements in the periodical system and the most important compounds of these elements. Formation of compounds as a consequence of the electronoc structure of the elements.
3. Introduction to organic chemistry
Description of the most important classes of compounds and of the functional groups. Principal reactivity of these functional groups.
Rection mechanisms: SN1- and SN2-reactions, electrophilic aromatic subtitutions, eliminations (E1 and E2), addition reactions (C=C and C=O double bonds). Chemistry of carbony and carboxyl groups.
|Lecture notes||C.E. Mortimer & U. Müller, CHEMIE, 12. Auflage, Thieme: Stuttgart, 2015 (ISBN 978-3-13-484312-5)|
|Literature||Th.L.Brown, H.E.LeMay, B.E.Bursten; Chemie, 10. Auflage, Pearson Studium, München, 2007 (ISBN 3-8273-7191-0)|
C.E.Housecroft, E.C.Constable, Chemistry, 3rd Edition, Pearson, Harlow (England), 2006 (ISBN 0-131-27567-4)
D.W.Oxtoby, H.P.Gillis, N.H.Nachtrieb, Principles of Modern Chemistry, Fifth Edition, Thomson, London, 2002 (ISBN 0-03-035373-4)