Christophe Copéret: Katalogdaten im Frühjahrssemester 2022 |
| Name | Herr Prof. Dr. Christophe Copéret |
| Namensvarianten | Christophe Coperet |
| Lehrgebiet | Oberflächen- und Grenzflächen-Chemie |
| Adresse | Lab. für Anorganische Chemie ETH Zürich, HCI H 229 Vladimir-Prelog-Weg 1-5/10 8093 Zürich SWITZERLAND |
| Telefon | +41 44 633 93 94 |
| ccoperet@inorg.chem.ethz.ch | |
| Departement | Chemie und Angewandte Biowissenschaften |
| Beziehung | Ordentlicher Professor |
| Nummer | Titel | ECTS | Umfang | Dozierende | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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| 529-0131-00L | Inorganic Chemistry IV: (Nano-)Materials; Synthesis, Properties and Surface Chemistry | 4 KP | 3G | C. Copéret, A. Comas Vives | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Kurzbeschreibung | Einführung in Synthese und Eigenschaften von Feststoffen und von Nanomaterialien. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Lernziel | Kenntnis von Synthesen, Eigenschaften und Anwendungen von Feststoffen und von Nanomaterialien. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Inhalt | Klassifikation fester Stoffe; Synthese fester Stoffe; Stoffgruppen-Eigenschaften-Anwendungen: Nanomaterialien, Ionenverbindungen, Halbleiter, Intermetallische Phasen; Bindung und Bandstruktur; physikalische Methoden zur Charakterisierung von Festkörpern und ihrer Oberflächen. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Skript | auf dem Internet erhältlich. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Literatur | A. West, Solid State Chemistry and its Applications, Wiley 1989; U. Müller, Anorganische Strukturchemie, Teubner Taschenbuch 2006; R. Nesper, H.-J. Muhr, Chimia 52 (1998) 571; C.N.R. Rao, A. Müller, A.K. Cheetham, Nanomaterials, Wiley-VCH 2007. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Voraussetzungen / Besonderes | AC-II | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Kompetenzen |
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| 529-0132-AAL | Inorganic Chemistry III: Organometallic Chemistry and Homogeneous Catalysis Belegung ist NUR erlaubt für MSc Studierende, die diese Lerneinheit als Auflagenfach verfügt haben. Alle anderen Studierenden (u.a. auch Mobilitätsstudierende, Doktorierende) können diese Lerneinheit NICHT belegen. Dieser Kurs beinhaltet keine eigene Vorlesung, sondern bezieht sich auf die Vorlesung 529-0132-00L. | 4 KP | 9R | C. Copéret | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Kurzbeschreibung | Fundamental aspects of the organometallic chemistry ot the transition elements. Mechanistic homogeneous catalysis including oxidative additions, reductive eliminations and insertion reactions. Catalytic hydrogenation, carbonylation, C-C bond-forming and related reactions. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Lernziel | Towards an understanding of the fundamental coordination-chemical and mechanistic aspects of transition-metal chemistry relevant to homogeneous catalysis. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Inhalt | Fundamental aspects of the organometallic chemistry ot the transition elements. Mechanistic homogeneous catalysis including oxidative additions, reductive eliminations and insertion reactions. Catalytic hydrogenation, carbonylation, C-C bond-forming and related reactions. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Literatur | 1) Robert H. Crabtree, The Organometallic Chemistry of the Transition Metals, 6th Edition, Wiley, 2014, ISBN: 978-1-118-13807-6. A relatively concise but excellent introduction to organometallic chemistry. Strong textbook character, available as E-book 2) John F. Hartwig, Organotransition Metal Chemistry. From Bonding to Catalysis, University Science Books, 2010, ISBN: 978-1-891389-53-5. A more comprehensive standard work on organometallic chemistry. Several chapters written by various authors, partly specialized review-article style. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| 529-0142-00L | Advanced Organometallic and Coordination Chemistry: Learning from Nature and Industrial Processes Voraussetzung: Besuch der Lehrveranstaltung 529-0132-00L "Anorganische Chemie III: Metallorganische Chemie und Homogenkatalyse" | 6 KP | 3G | V. Mougel, C. Copéret | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Kurzbeschreibung | This class will discuss advanced concepts in organometallic, bio-inorganic and coordination chemistry, in the context of homogeneous and heterogeneous catalysis as well as enzymatic processes. The class will thus cover a broad range of catalytic transformations focusing on the sustainable and efficient use of feedstock molecules, exploring the parallel between industrial and biological systems. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Lernziel | Gain knowledge of catalytic transformations, relevant to processes found in industry and in Nature. Development of an extended molecular understanding of organometallic, bio-inorganic and coordination chemistry in relation to catalytic transformations. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Inhalt | Specific focus will be given to key reactions such as alkane functionalization and homologation, olefin metathesis and polymerization, oxidation, processes related to conversion of C1 molecules (CH4 and CO2), CO/H2 to hydrocarbons (Fischer-Tropsch) and N2/H2 to ammonia (Haber-Bosch) as well as the corresponding enzymatic counterparts. The fundamental underlying principle of the associated elementary steps and reaction mechanisms involved in these processes, that include C-H activation, O/N-atom transfer reactions, N-N, C-O and C-C bond cleavage and formation will be discussed in details exploiting Molecular Orbital theory and spectroscopy. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Skript | A script is provided on Ilias. It is expected that the students will consult the accompanying literature. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Literatur | Books 1) R. Crabtree: the Organometallic Chemistry of Transition Metals – Wiley, 5th Edition 2) TA Albright, JB Burdett, MH Whangbo: Orbital Interactions in Chemistry – Wiley Interscience 3) Y. Jean: Molecular Orbitals of Transition Metal complexes – Oxford University Press 4) Bertini, Gray, Stiefel, Valentine: Biological Inorganic Chemistry – University Science Books | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Voraussetzungen / Besonderes | it is expected that students will have knowledge of AC-III or similar class/level. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Kompetenzen |
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| 529-0199-00L | Inorganic and Organometallic Chemistry | 0 KP | 2K | H. Grützmacher, M. Bezdek, C. Copéret, D. Günther, M. Kovalenko, T. Lippert, V. Mougel, P. Steinegger | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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