Antonio Togni: Catalogue data in Spring Semester 2018

Award: The Golden Owl
Name Prof. em. Dr. Antonio Togni
FieldMetallorganische Chemie
Address
Lab. für Anorganische Chemie
ETH Zürich, HCI G 139
Vladimir-Prelog-Weg 1-5/10
8093 Zürich
SWITZERLAND
Telephone+41 44 632 22 36
E-mailantonio.togni@inorg.chem.ethz.ch
DepartmentChemistry and Applied Biosciences
RelationshipProfessor emeritus

NumberTitleECTSHoursLecturers
529-0132-AALInorganic Chemistry III: Organometallic Chemistry and Homogeneous Catalysis
Enrolment ONLY for MSc students with a decree declaring this course unit as an additional admission requirement.

All other students (e.g. incoming exchange students, doctoral students) CANNOT enrol for this course unit.
4 credits9RA. Togni, A. Mezzetti
AbstractFundamental aspects of the organometallic chemistry ot the transition elements. Mechanistic homogeneous catalysis including oxidative additions, reductive eliminations and insertion reactions. Catalytic hydrogenation, carbonylation, C-C bond-forming and related reactions.
ObjectiveTowards an understanding of the fundamental coordination-chemical and mechanistic aspects of transition-metal chemistry relevant to homogeneous catalysis.
ContentFundamental aspects of the organometallic chemistry ot the transition elements. Mechanistic homogeneous catalysis including oxidative additions, reductive eliminations and insertion reactions. Catalytic hydrogenation, carbonylation, C-C bond-forming and related reactions.
Literature1) Robert H. Crabtree, The Organometallic Chemistry of the Transition Metals, 6th Edition, Wiley, 2014, ISBN: 978-1-118-13807-6.
A relatively concise but excellent introduction to organometallic chemistry. Strong textbook character, available as E-book

2) John F. Hartwig, Organotransition Metal Chemistry. From Bonding to Catalysis, University Science Books, 2010, ISBN: 978-1-891389-53-5.
A more comprehensive standard work on organometallic chemistry. Several chapters written by various authors, partly specialized review-article style.
529-0142-00LAdvanced Organometallic Chemistry
Prerequisites: successful participation in 529-0132-00L "Inorganic Chemistry III: Organometallic Chemistry and Homogeneous Catalysis".
6 credits3GA. Togni, C. Copéret
AbstractAdvanced organometallic chemistry, homogeneous catalysis and related heterogeneous processes.
Selected topics include: chiral metallocenes and their application in enantioselective reactions, Pd-catalyzed C-C bond forming reactions, olefin metathesis, alkane conversion (C-H ad C-C bond activation), C1 chemistry, processes inorganic and organic fluorine chemistry.
ObjectiveDevelopment of an extended understanding of the (organometallic) chemistry associated with homogeneous and heterogeneous catalytic processes
ContentAdvanced organometallic chemistry and homogeneous catalysis. Selected topics include: chiral metallocenes and their application in enantioselective reactions, Pd-catalyzed C-C bond forming reactions, C-H activation, olefin metathesis, inorganic and organic fluorine chemistry.
Lecture notesA script is provided. It is expected that the students will consult the accompanying literature.
529-0199-00LInorganic and Organometallic Chemistry0 credits2KH. Grützmacher, C. Copéret, D. Günther, M. Kovalenko, A. Mezzetti, A. Togni
Abstract
Objective
529-0961-00LFundamental Aspects of Chemistry with an Educational Focus A4 credits2AA. Togni, R. Alberto
AbstractSelected topics in general chemistry:
1) Acids, super acids, acidity functions, and unconventional solvents
2) Inorganic medicinal chemistry
3) History of radioactivity and modern radiochemistry
4) Molecular geometry and structure
ObjectiveIn this course unit, participants acquire extended and more in-depth knowledge of selected chemistry topics. The selection is based to a large extent on the partial aspects of chemistry that are typically taught at high school. By gaining a broader understanding, teachers are put in a position where they can comprehend the topics that are to be taught in a wider and, to some extent, unconventional context and critically process these in respect of their teachability and learnabiltiy. At the same time, interrelationships between the classical sub-disciplines of chemistry are highlighted, along with the unique features of chemistry as one of the central natural sciences.
ContentContent of the four modules:
1) Acids, super acids, acidity functions, non acqueous media, and unconventional solvents.
2) Inorganic medicinal chemistry: Metals in biological systems, metal-containing drugs.
3) History of radioactivity and modern radiochemistry: From the discovery of radioactivity to modern element synthesis.
4) Molecular geometry and structure: From the VSEPR model to the electron localization function (ELF), hypervalent compounds and their applications.
Lecture notesFolien und ausgewählte Literatur werden zur Verfügung gestellt.
LiteratureAusgewählte Artikel aus der Primärliteratur werden vorgestellt, kommentiert und zur Lektüre empfohlen.
Prerequisites / NoticeFV A (gelesen im Frühjahrsemester) und FV B (gelesen im Herbstsemester) bauen nicht aufeinander. Die Reihenfolge der Belegung ist somit indifferent.